Yes you can and depending on which version your core is you can use OSD (old and removed from some versions) or Provisioning and just found out which switches you need to set to capture the image like these in this article for ImageW Use Imagew v2 to deploy image but leave D: intact? Just make sure you choose the correct USB drive letter. Now you can add the ImageW.exe to WinPE and load it on a USB stick and run that as well to capture the image on it.
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